Protocol for Practical Classes

 

Experiment 6 - Carbohydrates - caracterization


Materials:

Provided by the students :

Paper filters

From the laboratory

starch solution prepared on Experiment 5

4 assays tubes

3 pippetes

concentrated sulfur acid– CARE– corrosive

bequer

Molisch test solution

Lugol solution

Satturated solution of Ammonion sulfate

Ethili alcohol (P.A.)


Metods:

Molisch test:

Tranfer 2 mL of the starch solution to the Tube1 (do not agitate, avoid tranfering the pellet)

Add three drops of the Molisch solution

Add to teh tube 1,2 ml of concentrated sulfur acid (draining it on the tube wall and not dropping it in the middle of the solution)

Write down the result.

Iodine reaction:

Tranfer 2 mL of the starch solution to the Tube2

Add 5mL of distilled water

Add a drop of the Lugol reagente

Warm the Tube 2 to 90oC for 5 min and observe the alterations

Let the Tube in rest to cool and observe the alterations

Write all the results down.

Precipitation reaction (I)

Tranfer 5ml of the starch solution to a bequer (do not agitate)

Add 3ml to the Ammonion sulfate solution to the bequer, while agitating the solution

Let the solution in rest for 10minutes

Filter the solution leaving the pellet in teh bequer

Add 1 drop pf the Lugol reagente to the pellet and another to the filtered material

Write down the results

Precipitation reaction (II)

TRanfer 1ml of the starch solution to the Tube 3

Add 5ml of Ethanol, and agitate ir

Repeat the four last steps of the previous reaction

Write down the results


Objectives :

To understand the mechanism of starch solubilization

To caractherize the starch as a polissacharide

To caractherize the starch monomers

To understand the interaction between starch and Iodine


Report suggestions:

Explain why the starch, besides its polarity, is hardly solubilizates in water under some conditions

Explain how the starch interact with the iodine and how the color changes observed occur.


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